332062
Dichlorobis(tributylphosphine)nickel(II)
Synonym(s):
NSC 54233
About This Item
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reaction suitability
core: nickel
reagent type: catalyst
mp
43-45 °C (lit.)
storage temp.
2-8°C
SMILES string
Cl[Ni]Cl.CCCCP(CCCC)CCCC.CCCCP(CCCC)CCCC
InChI
1S/2C12H27P.2ClH.Ni/c2*1-4-7-10-13(11-8-5-2)12-9-6-3;;;/h2*4-12H2,1-3H3;2*1H;/q;;;;+2/p-2
InChI key
KPFOFXWYYUNJOZ-UHFFFAOYSA-L
Application
- Wenkert arylations
- Regioselective [2+2+2] cycloadditions
- Polymerization reactions
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
332062-VAR:
332062-25G:4548173301563
332062-BULK:
332062-5G:4548173301570
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Articles
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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