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317365

Sigma-Aldrich

Tetramethylammonium triacetoxyborohydride

95%

Synonym(s):

triacetoxyboranuide

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10 G
¥27,100
50 G
¥72,600

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10 G
¥27,100
50 G
¥72,600

About This Item

Linear Formula:
(CH3)4N(CH3CO2)3BH
CAS Number:
109704-53-2
Molecular Weight:
263.10
Beilstein:
8238791
MDL number:
MFCD00012196
UNSPSC Code:
12352116
PubChem Substance ID:
24859075
NACRES:
NA.22

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Assay

95%

form

solid

reaction suitability

reagent type: reductant

mp

93-98 °C (lit.)

functional group

amine

SMILES string

C[N+](C)(C)C.CC(=O)O[BH-](OC(C)=O)OC(C)=O

InChI

1S/C6H10BO6.C4H12N/c1-4(8)11-7(12-5(2)9)13-6(3)10;1-5(2,3)4/h7H,1-3H3;1-4H3/q-1;+1

InChI key

LCFZZOGKVOTFPU-UHFFFAOYSA-N

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Related Categories

Application

Selective reducing agent.[1][2][3]

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H261,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2

Target Organs

Respiratory system

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 3: Spontaneously combustible substances and water- reactive materials
Metal hydrides
Hazardous rank I
1st spontaneously combustible materials and water reactive materials

JAN Code

317365-VAR:
317365-BULK:
317365-50G:
317365-10G:
317365-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBQ7275
SHBM3162
SHBM7450
SHBL5845
SHBH1515V

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Ning Shangguan et al.
Organic letters, 9(6), 1093-1096 (2007-02-27)
A formal synthesis of psymberin (irciniastatin A) is presented. Notable features of the synthesis include the chemo-, regio-, and stereoselective oxidation of a 1,3-disubstituted allene, a configuration-dependent spirodiepoxide opening, the efficient syntheses of functionalized trans-2,6-disubstituted pyrans, and the union of
Chemtracts, 5, 188-192 (1992)
Tetrahedron Letters, 44, 7239-7243 (2003)

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