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275913

Sigma-Aldrich

Tricarbonyl(cyclooctatetraene)iron(II)

98%

Synonym(s):

1,3,5,7-Cyclooctatetraeneiron tricarbonyl, Cyclooctatetraenetricarbonyliron, NSC 167370, NSC 168049

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About This Item

Linear Formula:
C8H8Fe(CO)3
CAS Number:
Molecular Weight:
244.02
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

reaction suitability

core: iron
reagent type: catalyst

mp

93-95 °C (lit.)

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=CC=CC=C1

InChI

1S/C8H8.3CO.Fe/c1-2-4-6-8-7-5-3-1;3*1-2;/h1-8H;;;;/b2-1-,3-1-,4-2-,5-3-,6-4-,7-5-,8-6-,8-7-;;;;

InChI key

XAOCYVWRKJTXOL-CJNMVQMASA-N

Application

Catalyst for:
  • Light-driven hydrogen generation via reduction of water
  • Growth of multiwalled carbon nanotubes
  • Tandem isomerization-aldol condensation of allylic alcohols
  • Hydrogenation of anthracene and nitrogen heterocycles under water-gas shift conditions

Used:
  • For VPE-growth of iron-doped indium phosphide by metal organic chemical vapor deposition (MOCVD)
  • As sensitizer for isomerization of norbornadiene in solar-energy storage

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

275913-1G:
275913-VAR:
275913-250MG:
275913-BULK:


Certificates of Analysis (COA)

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