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26253

Sigma-Aldrich

(3-Chloropropyl)trimethylsilane

≥97.0%

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About This Item

Empirical Formula (Hill Notation):
C6H15ClSi
CAS Number:
2344-83-4
Molecular Weight:
150.72
Beilstein:
1732625
EC Number:
219-059-0
MDL number:
MFCD00045299
UNSPSC Code:
12352100
PubChem Substance ID:
57648158
NACRES:
NA.22

Assay

≥97.0%

refractive index

n20/D 1.431

bp

151 °C (lit.)

density

0.878 g/mL at 20 °C (lit.)

functional group

chloro

SMILES string

C[Si](C)(C)CCCCl

InChI

1S/C6H15ClSi/c1-8(2,3)6-4-5-7/h4-6H2,1-3H3

InChI key

QXDDDCNYAAJLBT-UHFFFAOYSA-N

Application

(3-Chloropropyl)trimethylsilane has been used in the preparation of:
  • 8-(3-trimethylsilylpropoxy)quinolone under phase transfer catalytic conditions[1]
  • 5-trimethylsilyl pentanol[2]
  • N-(tri-methylsilylalkyl)diamines[3]

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

120.2 °F - closed cup

Flash Point(C)

49 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

26253-5ML-F:
26253-VAR-F:
26253-25ML-F:
26253-BULK-F:

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Certificates of Analysis (COA)

Lot/Batch Number
BCBR4469V
BCBM4986V
BCBF3398V
434649/1
410108/1

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New deoxynojirimycin derivatives as potent inhibitors of intestinal a-glucohydrolases.
Lesur B, et al.
Bioorganic & Medicinal Chemistry Letters, 7(3), 355-360 (1997)
Silyl Modification of Biologically Active Compounds. 10. Lipid Type Organosilicon Derivatives of 8-Hydroxyquinoline and N-(2-Hydroxyethyl)-1, 2, 3, 4-tetrahydro (sila, iso) quinolines.
Segal I, et al.
Chemistry of Heterocyclic Compounds, 41(5), 613-624 (2005)
Organosilicon Compounds. Part V. Synthesis of N-(trimethylsilylalkyl) diamines and N-(trimethylsilylalkyl)-N'-(2-mercaptoethyl) diamines.
Thames SF and Edwards LH.
J. Chem. Soc. Sect. C, 2339-2342 (1968)

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