247650

Hexarhodium(0) hexadecacarbonyl

Rh 57-60 % (approx.)

• Synonym(s): Rhodium(0) carbonyl
• Linear Formula: Rh₆(CO)₁₆
• CAS Number: 28407-51-4
• Molecular Weight: 1065.59
• EC Number: 249-009-3
• MDL number: MFCD00011206
• UNSPSC Code: 12161600
• PubChem Substance ID: 24854881
• NACRES: NA.22

Properties

• composition: Rh, 57-60% (approx.)
• reaction suitability: core: rhodium; reagent type: catalyst
• SMILES string: [Rh].[Rh].[Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/16CO.6Rh/c16*1-2;;;;;;
• InChI key: SZQABOJVTZVBHE-UHFFFAOYSA-N

Description

Application

Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds

Widely used organometallic catalyst. Applications include the hydroformylation of olefins.[1][2]

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302 + H312 + H332
• Precautionary Statements: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves