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227722

Sigma-Aldrich

Silver hexafluorophosphate

98%

Synonym(s):

Silver(I) hexafluorophosphate

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1 G
¥8,940
10 G
¥50,900

¥8,940

Estimated to ship onApril 15, 2025

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1 G
¥8,940
10 G
¥50,900

About This Item

Linear Formula:
AgPF6
CAS Number:
26042-63-7
Molecular Weight:
252.83
EC Number:
247-428-6
MDL number:
MFCD00003415
UNSPSC Code:
12161600
PubChem Substance ID:
24853649
NACRES:
NA.22

¥8,940

Estimated to ship onApril 15, 2025

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Quality Level

100

Assay

98%

form

solid

reaction suitability

core: silver
reagent type: catalyst

mp

102 °C (dec.) (lit.)

SMILES string

[Ag+].F[P-](F)(F)(F)(F)F

InChI

1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1

InChI key

SCQBROMTFBBDHF-UHFFFAOYSA-N

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General description

Silver hexafluorophosphate can be used as a catalyst for the sulfimidation, hydrogenation of aldehydes to alcohols, and hydroacyloxylation of alkynes with carboxylic acids[1][2][3].

Application

Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.[4] Preparation of supramolecular networks of Ag(I) complexes.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

227722-BULK:
227722-250MG:
227722-VAR:
227722-1G:4548173119953
227722-50G:4548173119960
227722-10G:4548173119946

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX1424
MKCX0218
MKCR7394
MKCS6383
MKCQ6242

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Gold (I)-catalyzed addition of carboxylic acids to alkynes
Chary B, et al.
The Journal of Organic Chemistry, 75, 7928-7931 (2010)
Journal of Organometallic Chemistry, 692, 4093-4093 (2007)
Silver-Catalyzed Hydrogenation of Aldehydes in Water
Jia Z, et al.
Angewandte Chemie (International Edition in English), 52, 11871-11874 (2013)
Silver-Catalyzed Enantioselective Sulfimidation Mediated by Hydrogen Bonding Interactions
Annapureddy R, et al.
Angewandte Chemie (International Edition in English), 133, 7999-8005 (2021)
Keith A. Hirsch et al.
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar

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