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Safety Information

226130

Sigma-Aldrich

3-Bromo-1,2-propanediol

97%

Synonym(s):

α-Glycerol bromohydrin

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About This Item

Linear Formula:
CH2BrCHOHCH2OH
CAS Number:
4704-77-2
Molecular Weight:
154.99
Beilstein:
1719124
EC Number:
225-186-2
MDL number:
MFCD00004711
UNSPSC Code:
12162002
PubChem Substance ID:
24853545
NACRES:
NA.23

Assay

97%

form

liquid

refractive index

n20/D 1.518 (lit.)

bp

72-75 °C/0.2 mmHg (lit.)

density

1.771 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

OCC(O)CBr

InChI

1S/C3H7BrO2/c4-1-3(6)2-5/h3,5-6H,1-2H2

InChI key

SIBFQOUHOCRXDL-UHFFFAOYSA-N

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Application

Protecting reagent for carbonyl functions.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

226130-VAR:
226130-BULK:
226130-25G:
226130-5G:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A R Jones et al.
Journal of applied toxicology : JAT, 16(1), 57-63 (1996-01-01)
(R,S)- and (R)-3-Bromopropan-1,2-diol (alpha-bromohydrin) produced diuresis and glucosuria when administered to male rats but had no effect on the metabolic activity of rat kidney tubules in vitro. The oxidation products (R,S)-3-bromolactate and 3-bromopyruvate produced brief phases of diuresis but not
A R Jones et al.
Journal of reproduction and fertility, 108(1), 95-100 (1996-09-01)
Boar spermatozoa incubated with glycerol 3-phosphate as substrate produced CO2 and an accumulation of dihydroxyacetone phosphate and fructose-1,6-bisphosphate. The rate of oxidation of glycerol 3-phosphate was decreased, as was the production of CO2 and the two glycolytic intermediates, in the

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