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224847

Sigma-Aldrich

Iodine monobromide

98%

Synonym(s):

Bromoiodine

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¥47,700

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50 G
¥16,300
250 G
¥47,700

About This Item

Linear Formula:
IBr
CAS Number:
Molecular Weight:
206.81
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

¥16,300


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Quality Level

Assay

98%

form

solid

mp

42-50 °C (lit.)

density

4.416 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

BrI

InChI

1S/BrI/c1-2

InChI key

CBEQRNSPHCCXSH-UHFFFAOYSA-N

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General description

Iodine monobromide is an interhalogen compound used as an electrophile in the synthesis of polyketide structural units.[1]

Iodine monobromide (IBr) is a powerful iodinating agent employed in organic synthesis. IBr is commonly used in cleavage of carbon–metal bonds, electrophilic addition to alkenes, α-bromination of steroidal ketones and aldehydes, and in diastereoselective cyclizations of homoallylic carbonates.[2]

Application

Electrophile employed in a new synthetic approach to polyketide structural units.[3]

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

224847-10KG:
224847-BULK:
224847-500G:
224847-VAR:
224847-250G:4548173986791
224847-50G:4548173986807
224847-250G-PW:
224847-50G-PW:
224847-5KG:


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The Thermodynamic Constants of Iodine Monobromide
McMorris, et al.
Journal of the American Chemical Society, 53, 2625-2631 (1931)
Kai Liu et al.
Organic letters, 8(23), 5393-5395 (2006-11-03)
[Structure: see text] A strategically novel approach to the formation of syn-1,3-diol mono- and diethers through electrophilic activation of homoallylic alkoxymethyl ethers has been developed. The resulting polyketide-like synthetic fragments are generated in good yield and with excellent stereocontrol. A
Iodine Monobromide
Brisbois RG, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-5 (2001)
Z R Zunnunov
Terapevticheskii arkhiv, 82(1), 24-27 (2010-04-07)
to evaluate the efficiency of iodide-bromine balneotherapy (IBB) in patients with coronary heart disease (CHD) concurrent with chronic obstructive pulmonary disease (COPD). Sixty-six patients with CHD, Functional Class HII stable angina on exertion concurrent with mild and moderate COPD were
[A method for preparing iodine and iodine bromide baths with the presence of molecular iodine].
I I Gusarov et al.
Voprosy kurortologii, fizioterapii, i lechebnoi fizicheskoi kultury, (2)(2), 62-63 (1989-03-01)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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