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Safety Information

220973

Sigma-Aldrich

Titanium(III) chloride

ReagentPlus®, powder

Synonym(s):

Titanium trichloride

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About This Item

Linear Formula:
TiCl3
CAS Number:
7705-07-9
Molecular Weight:
154.23
EC Number:
231-728-9
MDL number:
MFCD00011266
UNSPSC Code:
12352301
PubChem Substance ID:
24853202

product line

ReagentPlus®

form

powder

reaction suitability

reagent type: catalyst
core: titanium

mp

440 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl

InChI

1S/3ClH.Ti/h3*1H;/q;;;+3/p-3

InChI key

YONPGGFAJWQGJC-UHFFFAOYSA-K

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Application

Used for the vapor-phase formation of intermetallic compounds with ultrafine particle size.
Used with tert-butylhydroperoxide in an alcoholic solvent to promote the reductive coupling of aryl aldehydes to 1,2-diols.[1]

Catalyst for:
hydrogen desorption properties[2]
Nitrogen-nitrogen reductive bond cleavage[3]

Reagent for photocatalyst synthesis[4]

Precursor for the preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeletons[5]

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H250,H314

Hazard Classifications

Pyr. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

220973-5G:4548173117768
220973-BULK:
220973-5G-PW:
220973-VAR:
220973-25G:4548173117751
220973-25G-PW:
220973-100G:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN8054V
MKBN8055V
MKBN6290V
MKBN3841V
MKBN2792V

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European Journal of Organic Chemistry, 4050-4050 (2007)
S. Isobe, et al.,
Applied Physics Letters, 99 (2011)
Shuxi Dai et al.
Nanoscale research letters, 5(11), 1829-1835 (2010-12-03)
Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy
D. Meroni, et al
Catalysis Today, 161, 169-174 (2011)
Gnana S Siluvai et al.
Biochemistry, 48(51), 12133-12144 (2009-11-20)
Sco-like proteins contain copper bound by two cysteines and a histidine residue. Although their function is still incompletely understood, there is a clear involvement with the assembly of cytochrome oxidases that contain the Cu(A) center in subunit 2, possibly mediating
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