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216186

Sigma-Aldrich

Potassium selenocyanate

reagent grade, 97%

Synonym(s):

Selenocyanic acid potassium

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About This Item

Linear Formula:
KSeCN
CAS Number:
3425-46-5
Molecular Weight:
144.08
Beilstein:
3912121
EC Number:
222-320-1
MDL number:
MFCD00011366
UNSPSC Code:
12352302
PubChem Substance ID:
24852939
NACRES:
NA.23

grade

reagent grade

Assay

97%

form

solid

technique(s)

NMR: suitable

mp

100 °C

SMILES string

[K][Se]C#N

InChI

1S/CHNSe.K/c2-1-3;/h3H;/q;+1/p-1

InChI key

KYEKHFSRAXRJBR-UHFFFAOYSA-M

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General description

Potassium selenocyanate is a crystalline solid and a reagent for the conversion of alkyl halides to nitriles, and the production of pharmaceutical intermediates. It also finds application in the field of energy storage devices.

Application

Potassium selenocyanate can be used as a:
  • Redox-active electrolyte to enhance the performance of carbon-based supercapacitors.
  • Starting material for the one-pot stereoselective synthesis of alkyl styryl selenides.
  • Precursor to synthesize Cu and Ni complexes with antioxidant/anti-inflammatory activities.
  • Selenylating agent to prepare stereoselective selenoglycosides and selenium-linked disaccharides.

Signal Word

Danger

Hazard Statements

H300,H331,H373,H410

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Poisonous substance

PRTR

Class I Designated Chemical Substances

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

216186-BULK:
216186-25KG:4548173250878
216186-2.5KG:4548173117065
216186-1KG:
216186-10G:4548173117058
216186-VAR:
216186-250G:4548173117072
216186-50G:4548173117089

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Stereoselective synthesis of alkyl styryl selenides in one-pot: a straightforward approach by in situ dialkyl diselenide formation under transition metal-free conditions
Adrian A Heredia, et al.
Royal Society of Chemistry Advances, 5, 105699-105706 (2015)
Synthesis, structural characterization and antioxidant/anti-inflammatory activity of pentacoordinated bis(isoselenocyanato) and bis(isothiocyanato) CuII and NiII complexes with Me5dien: Crystal structure of [Cu(Me5dien)(NCSe)2]
Zacharias D. Georgousis, et al.
Journal of Molecular Structure, 837, 30-37 (2007)
Redox activity of selenocyanate anion in electrochemical capacitor application
Paulina Bujewska, et al.
Synthetic Metals, 253, 62-72 (2019)
Journal of the Chemical Society. Chemical Communications, 860-860 (1991)
J. Ind. Chem. Soc., 62, 800-800 (1985)
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