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203483

Sigma-Aldrich

Bis(triphenylphosphine)iridium(I) carbonyl chloride

99.99%

Synonym(s):

IrCl(CO)(PPh3)2, Chlorocarbonylbis(triphenylphosphine)iridium(I), Iridium(I)bis(triphenylphosphine)carbonyl chloride

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About This Item

Linear Formula:
[(C6H5)3P]2IrCl(CO)
CAS Number:
14871-41-1
Molecular Weight:
780.25
EC Number:
238-941-6
MDL number:
MFCD00009590
UNSPSC Code:
12352300
PubChem Substance ID:
24852175

Assay

99.99%

SMILES string

Cl[Ir].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

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Application

Catalyst precursor for hydrogenations, decarbonylationof acyl halides, and the hydrosilation and hydroboration of alkenes

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
37497MJ
05605CH
04819AX
03026HW
19209PD

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Westcott, S. A.; Blom, H. P. et al.
Journal of the American Chemical Society, 114, 8863- 8863 (1992)
Westcott, S. A.; Marder, T. B. et al.
Synlett, 71, 930-930 (1993)

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