Skip to Content
Merck
All Photos(1)

Documents

Safety Information

165263

Sigma-Aldrich

Ethyl 2-ethylacetoacetate

90%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
CH3COCH(C2H5)COOC2H5
CAS Number:
607-97-6
Molecular Weight:
158.19
Beilstein:
636286
EC Number:
210-151-6
MDL number:
MFCD00039898
UNSPSC Code:
12352100
PubChem Substance ID:
24850132
NACRES:
NA.22

Assay

90%

form

liquid

refractive index

n20/D 1.421 (lit.)

bp

87-189 °C/743 mmHg (lit.)

density

0.981 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C(CC)C(C)=O

InChI

1S/C8H14O3/c1-4-7(6(3)9)8(10)11-5-2/h7H,4-5H2,1-3H3

InChI key

OKANYBNORCUPKZ-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Ethyl 2-ethylacetoacetate was used in the synthesis of 2-alkylidenetetrahydrofurans, diphenyllead(IV) thiosemicarbazonates and pyrazolonates. It was used as starting reagent in the synthesis of 2-ethylfumaric acid.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

156.2 °F - closed cup

Flash Point(C)

69 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

165263-BULK:
165263-25G:
165263-100G:
165263-VAR:
165263-1KG:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Diphenyllead (IV) thiosemicarbazonates and pyrazolonates: Synthesis and characterization.
Casas JS, et al.
Polyhedron, 28(5), 1029-1039 (2009)
Hans Raj et al.
Applied microbiology and biotechnology, 94(2), 385-397 (2011-10-19)
Methylaspartate ammonia lyase (MAL; EC 4.3.1.2) catalyzes the reversible addition of ammonia to mesaconate to give (2S,3S)-3-methylaspartate and (2S,3R)-3-methylaspartate as products. MAL is of considerable biocatalytic interest because of its potential use for the asymmetric synthesis of substituted aspartic acids
Efficient synthesis of functionalized furans and benzofurans based on a '[3+ 2] cyclization/oxidation'strategy.
Bellur E, et al.
Tetrahedron Letters, 46(13), 2185-2187 (2005)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service