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163015
Thallium(III) nitrate trihydrate
Synonym(s):
TTN, Thallium trinitrate
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25 G
¥20,700
100 G
¥60,300
About This Item
Linear Formula:
Tl(NO3)3 · 3H2O
CAS Number:
Molecular Weight:
444.44
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
reaction suitability
core: thallium
reagent type: catalyst
mp
102-105 °C (lit.)
SMILES string
O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
InChI
1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3
InChI key
ZCPIKMRXMBJLCP-UHFFFAOYSA-N
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Application
Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds,[1] for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement,[2] for the selective hydrolysis of thioacetals to carbonyl compounds[3] and for a general synthetic method to 19-norsteroids.[4] Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.[5]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
PRTR
Class I Designated Chemical Substances
FSL
Group 1: Oxidizing solids
Nitrates
Hazardous rank I
1st oxidizing solid
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
163015-VAR:
163015-100G:4548173108636
163015-25G:4548173108643
163015-5G:4548173108650
163015-BULK:
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Articles
Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis
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Thallium(III) nitrate trihydrate(CASRN:13453-38-8)ですが、SDSでは毒劇法に非該当の記載です。一方、WEBでは毒劇法の劇物の記載です。どちらが正しいのでしょうか。 水和物を原体とするか製剤とするかで判断が異なるのでしょうか。
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