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Safety Information

14826

Sigma-Aldrich

(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine

≥98.0% (CHN)

Synonym(s):

(R)-(+)-N,N-Bis(2-diphenylphosphinoethyl)-α-methylbenzylamine

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About This Item

Empirical Formula (Hill Notation):
C36H37NP2
CAS Number:
Molecular Weight:
545.63
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:

Assay

≥98.0% (CHN)

optical activity

[α]20/D +4.5±0.7°, c = 1% in acetone

SMILES string

C[C@@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5

InChI

1S/C36H37NP2/c1-31(32-17-7-2-8-18-32)37(27-29-38(33-19-9-3-10-20-33)34-21-11-4-12-22-34)28-30-39(35-23-13-5-14-24-35)36-25-15-6-16-26-36/h2-26,31H,27-30H2,1H3/t31-/m1/s1

InChI key

ZVNAHLJBPYKGBV-WJOKGBTCSA-N

Other Notes

Diphosphine ligand for iridium-cat. reduction of unsaturated ketones to allylalcohols

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

14826-500MG:
14826-BULK:
14826-VAR:


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C. Bianchini et al.
Organometallics, 14, 1489-1489 (1995)

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