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128023

Sigma-Aldrich

2-Amino-5-bromothiazole monohydrobromide

97%

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About This Item

Empirical Formula (Hill Notation):
C3H3BrN2S · HBr
CAS Number:
61296-22-8
Molecular Weight:
259.95
EC Number:
262-699-0
MDL number:
MFCD00012712
UNSPSC Code:
12352100
PubChem Substance ID:
24847815
NACRES:
NA.22

Assay

97%

form

solid

mp

165 °C (dec.) (lit.)

functional group

bromo

SMILES string

Br[H].Nc1ncc(Br)s1

InChI

1S/C3H3BrN2S.BrH/c4-2-1-6-3(5)7-2;/h1H,(H2,5,6);1H

InChI key

NUSVDASTCPBUIP-UHFFFAOYSA-N

Application

2-Amino-5-bromothiazole monohydrobromide was used in the preparation of N-(5-Bromo-2-thiazolyl)-2-acetylamino-2-ethoxycarbonyl-3-(2-furyl)-propanamide[1].

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

128023-25G:
128023-VAR:
128023-5G:
128023-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCD4046
MKBF7379V
MKBH1555V
MKBF7379
MKBD6266

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T Kitagawa et al.
Chemical & pharmaceutical bulletin, 49(3), 335-339 (2001-03-20)
N-Substituted 2-acetylamino-2-ethoxycarbonyl-3-(2-furyl)propanamides (8) were synthesized through the reaction of amines (13) with 2-acetylamino-2-ethoxycarbonyl-3-(2-furyl)propanoic acid (3b), which was prepared via condensation of 2-(bromomethyl)furan (10b) with diethyl acetamidomalonate, followed by partial hydrolysis of the resultant diethyl ester (3a) in the presence of

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