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117498

Sigma-Aldrich

1,2-Diaminopropane

99%

Synonym(s):

1,2-Propanediamine, Propylenediamine

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About This Item

Linear Formula:
CH3CH(NH2)CH2NH2
CAS Number:
78-90-0
Molecular Weight:
74.12
Beilstein:
605274
EC Number:
201-155-9
MDL number:
MFCD00008089
UNSPSC Code:
12352100
eCl@ss:
39030209
PubChem Substance ID:
24847332
NACRES:
NA.22

vapor density

2.6 (vs air)

vapor pressure

14 mmHg ( 20 °C)

Assay

99%

autoignition temp.

680 °F

expl. lim.

11.1 %

refractive index

n20/D 1.446 (lit.)

bp

119-120 °C (lit.)

solubility

H2O: very soluble

density

0.87 g/mL at 25 °C (lit.)

SMILES string

CC(N)CN

InChI

1S/C3H10N2/c1-3(5)2-4/h3H,2,4-5H2,1H3

InChI key

AOHJOMMDDJHIJH-UHFFFAOYSA-N

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General description

1,2-Diaminopropane undergoes condensation with salicylaldehyde and its derivatives to form Schiff base. It reacts with formaldehyde and hydrogen peroxide in aqueous acidic solution to give cage peroxide, 1,6-diaza-3,4,8,9-tetraoxa-11-methylbicyclo[4.4.2]dodecane.

Application

1,2-Diaminopropane was used as model precursor in the electron induced deposition of amorphous carbon nitride films.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Flam. Liq. 3 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

93.2 °F - closed cup

Flash Point(C)

34 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water soluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

117498-250ML:
117498-500G:
117498-BULK:
117498-100G:
117498-1L:
117498-VAR:
117498-2KG:

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chi Chen et al.
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Cage peroxides having planar bridgehead nitrogen atoms.
Edward JT, et al.
Canadian Journal of Chemistry, 77(5-6), 1057-1065 (1999)
Maryam Ghiyasiyan-Arani et al.
Scientific reports, 6, 25231-25231 (2016-05-05)
In this work, copper pyrovanadate (Cu3V2O7(OH)2(H2O)2) nanoparticles have been synthesized by a simple and rapid chemical precipitation method. Different copper-organic complexes were used to control the size and morphology of products. The morphology and structure of the as-synthesized products were
Mononuclear and dinuclear chiral vanadium (V) complexes with tridentate Schiff bases derived from< i> R</i>(-)-1, 2-diaminopropane: Synthesis, structure, characterization and catalytic properties.
Romanowski G and Wera M.
Polyhedron, 29(13), 2747-2754 (2010)
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