34854-M

Chloroform

suitable for HPLC, ≥99.8%, amylene stabilized

• Synonym(s): Methylidyne trichloride, Trichloromethane
• Empirical Formula (Hill Notation): CHCl₃
• CAS Number: 67-66-3
• Molecular Weight: 119.38
• Beilstein: 1731042
• EC Number: 200-663-8
• MDL number: MFCD00000826
• UNSPSC Code: 12190000
• PubChem Substance ID: 329755063
• NACRES: NA.21

Properties

• grade: HPLC grade
• vapor density: 4.1 (vs air)
• vapor pressure: 160 mmHg ( 20 °C)
• Assay: ≥99.8%
• form: liquid
• quality: amylene stabilized
• technique(s): HPLC: suitable
• impurities: Free acid, in accordance; acetone, aldehyde, in accordance (nessler test); free chlorine (Cl), in accordance; ≤0.0005% non-volatile matter; ≤0.001% free acid (as HCl); <0.01% water (Karl Fischer)
• evapn. residue: ≤0.0005%
• color: APHA: ≤10
• transmittance: 250 nm, ≥50%; 260 nm, ≥85%; 280 nm, ≥99%
• refractive index: n20/D 1.445 (lit.)
• bp: 60.5-61.5 °C (lit.)
• mp: −63 °C (lit.)
• solubility: water: soluble (8.7 g/l at 23 °C (73 °F) - OECD Test Guideline 105)
• density: 1.48 g/mL at 25 °C; 1.492 g/mL at 25 °C (lit.)
• anion traces: chloride (Cl^-): in accordance
• cation traces: Pb: ≤0.05 mg/kg
• absorption: in accordance
• λ: H₂O reference
• UV absorption: λ: 250 nm A_max: ≤1.00; λ: 260 nm A_max: ≤0.30; λ: 280 nm A_max: ≤0.005
• suitability: passes test for reaction against H₂SO₄; passes test for suitability of determ. w. dithizone
• application(s): general analytical
• SMILES string: ClC(Cl)Cl
• InChI: 1S/CHCl3/c2-1(3)4/h1H
• InChI key: HEDRZPFGACZZDS-UHFFFAOYSA-N

Description

General description

Chloroform, a halogenated hydrocarbon, is widely employed as a solvent. Its photochemical degradation has been investigated in the presence of TiO₂ aqueous suspensions (wavelength range of 310-380nm).

Application

Chloroform has been employed for the ion exchange isolation of sulfatides from the urinary samples by using DEAE-cellulose membranes before the tandem mass spectrometric analysis. It has been used as a solvent for the Langmuir-Blodgett (LB) deposition of lipid bilayers over mica sheets (silver coated back).†

Other Notes

Important notice

• The article number 34854-4X2.5L-M will be discontinued. Please order the single bottle 34854-2.5L-M which is physically identical with the same exact specifications.
• The article number 34854-6X1L-M will be discontinued. Please order the single bottle 34854-1L-M which is physically identical with the same exact specifications.

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Safety Information

• Pictograms: GHS06,GHS08
• Signal Word: Danger
• Hazard Statements: H302,H315,H319,H331,H336,H351,H361d,H372
• Precautionary Statements: P201 - P260 - P264 - P280 - P304 + P340 + P311 - P403 + P233
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 - STOT SE 3
• Target Organs: Central nervous system
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable