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Key Documents

918105

Sigma-Aldrich

(MeBPI)2Ni

≥95%

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About This Item

Empirical Formula (Hill Notation):
C40H32N10Ni
CAS Number:
Molecular Weight:
711.44
UNSPSC Code:
12352103
NACRES:
NA.22

Quality Level

Assay

≥95%

form

crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Application

(MeBPI)2Ni is a redox-active shuttle developed in the Sevov lab for electrocatalytic cross-electrophile coupling reactions. When combined with (MeBPI)Ni-OAc (919365), (MeBPI)Ni-OAc enables the reductive coupling of a wide range of aryl, heteroaryl, or vinyl bromides with primary or secondary alkyl bromides.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Blaise L Truesdell et al.
Journal of the American Chemical Society, 142(12), 5884-5893 (2020-03-03)
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction can readily exceed the reducing potentials of chemical reductants to activate catalysts

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