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643645

Sigma-Aldrich

Silica, mesostructured

MCM-41 type (hexagonal)

Synonym(s):

Silica, Silicon dioxide

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About This Item

Linear Formula:
SiO2
CAS Number:
Molecular Weight:
60.08
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

form

powder

surface area

~1000 m2/g , BET

unit cell size

4.5-4.8 nm

pore size

0.98 cm3/g pore volume
2.1-2.7 nm pore size

bp

2230 °C (lit.)

mp

>1600 °C (lit.)

bulk density

0.34 g/mL

application(s)

battery manufacturing

SMILES string

O=[Si]=O

InChI

1S/O2Si/c1-3-2

InChI key

VYPSYNLAJGMNEJ-UHFFFAOYSA-N

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General description

Silica, mesostructured (MCM-41) is a part of low-density organized mesoporous silicate system which has a 2D hexagonal phase, prepared in the presence of quaternary ammonium halide surfactant. It has ordered and large pores with diameter in the range 1.5-10 nm and specific surface area of 1500 m2/g.[1][2]

Application

MCM-41 may be used as a base material that can be assembled with platinum complexes to develop luminescent oxygen sensing materials.[3] It may also be used as an adsorbent in CO2 capture application.[4] Surface functionalized MCM-41 may be used as a catalyst in the synthesis of bisphenol A.[5]

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Customers Also Viewed

In situ investigations on cetyltrimethylammonium surfactant/silicate systems, precursors of organized mesoporous MCM-41-type siliceous materials
Frasch J, et al.
Langmuir, 16(23), 9049-9057 (2000)
Adsorption of CO2-containing gas mixtures over amine-bearing pore-expanded MCM-41 silica: application for gas purification
Belmabkhout Y, et al.
Industrial & Engineering Chemistry Research, 49(1), 359-365 (2009)
Effect of surface functionalization of MCM-41-type mesoporous silica nanoparticles on the endocytosis by human cancer cells
Slowing I, et al.
Journal of the American Chemical Society, 128(46), 14792-14793 (2006)
Chiral mesostructured silica nanofibers of MCM-41
Wang B, et al.
Angewandte Chemie (International ed. in English), 45(13), 2088-2090 (2006)
Oxygen sensing materials based on mesoporous silica MCM-41 and Pt (II)-porphyrin complexes
Zhang H, et al.
Journal of Materials Chemistry, 15(31), 3181-3186 (2005)

Articles

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Mesoporous silica used in wastewater remediation, air cleaning, catalysis, bio-catalysis, and drug delivery.

Mesoporous silica used in wastewater remediation, air cleaning, catalysis, bio-catalysis, and drug delivery.

Mesoporous silica used in wastewater remediation, air cleaning, catalysis, bio-catalysis, and drug delivery.

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Questions

1–4 of 4 Questions  
  1. Is CTAB expected to be contained in product 643645?

    1 answer
    1. No, this material is not expected to contain CTAB as it is calcined at 550°C for 24 hours to remove the CTAB.

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  2. Is the surface density of silanol groups of Product 643645, Silica, mesostructured MCM-41 type (hexagonal), known?

    1 answer
    1. For Product 643645, Silica, mesostructured MCM-41 type (hexagonal), between 10 and 15 % of the silicon centers are hydroxylated.

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  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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  4. How does the storage temperature relate to shipping conditions?

    1 answer
    1. The storage conditions that a Sigma-Aldrich catalog and label recommend for products are deliberately conservative. For many products, long-term storage at low temperatures will increase the time during which they are expected to remain in specification and therefore are labeled accordingly. Where short-term storage, shipping time frame, or exposure to conditions other than those recommended for long-term storage will not affect product quality, Sigma-Aldrich will ship at ambient temperature. The products sensitive to short-term exposure to conditions other than their recommended long-term storage are shipped on wet or dry ice. Ambient temperature shipping helps to control shipping costs for our customers. At any time, our customers can request wet- or dry-ice shipment, but the special handling is at customer expense if our product history indicates that the product is stable for regular shipment.

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