The CO2 electroreduction reaction has been investigated on Cu(100) and Cu(111) surfaces in 0.1 m aqueous solutions of KClO4 , KCl, KBr, and KI electrolyte. The formation of ethylene and ethanol on these surfaces generally increased as the electrolyte anion was
Chemistry, an Asian journal, 10(9), 1987-1996 (2015-06-23)
A new family of energetic compounds, nitropyrazoles bearing a trinitromethyl moiety at the nitrogen atom of the heterocycle, was designed. The desirable high-energy dense oxidizers 3,4-dinitro- and 3,5-dinitro-1-(trinitromethyl)pyrazoles were synthesized in good yields by destructive nitration of the corresponding 1-acetonylpyrazoles.
Derivatives are common preprocessing tools, typically implemented as Savitzky-Golay (SG) smoothing derivatives. This work discusses the implementation and optimization of fourth-order gap derivatives (GDs) as an alternative to SG derivatives for processing infrared spectra before multivariate calibration. Gap derivatives approximate
Magnetic resonance in chemistry : MRC, 49(11), 689-692 (2011-10-18)
As previously demonstrated by Thurber and Tycko, the peak position of (79)Br in potassium bromide (KBr) allows one to determine the temperature of a spinning sample. We propose to adapt the original design by using a compact KBr tablet placed
Mutations in the SCN1A gene, which encodes the α1 subunit of voltage-gated sodium channels, cause generalized epilepsy with febrile seizures plus (GEFS+) and severe myoclonic epilepsy of infancy (SMEI). N1417H-Scn1a mutant rats are considered to be an animal model of
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