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Precise control of alloying sites of bimetallic nanoclusters via surface motif exchange reaction.

Nature communications (2017-11-18)
Qiaofeng Yao, Yan Feng, Victor Fung, Yong Yu, De-En Jiang, Jun Yang, Jianping Xie
ABSTRACT

Precise control of alloying sites has long been a challenging pursuit, yet little has been achieved for the atomic-level manipulation of metallic nanomaterials. Here we describe utilization of a surface motif exchange (SME) reaction to selectively replace the surface motifs of parent [Ag

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4-Nitrothiophenol, technical grade, 80%