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  • Single-molecule fluorescence studies reveal long-range electron-transfer dynamics through double-stranded DNA.

Single-molecule fluorescence studies reveal long-range electron-transfer dynamics through double-stranded DNA.

Chemphyschem : a European journal of chemical physics and physical chemistry (2009-01-30)
Manoj Kumbhakar, Alexander Kiel, Haridas Pal, Dirk-Peter Herten
ABSTRACT

Complex dynamics of combined long-range fluorescence resonance energy transfer (FRET) and short-range electron transfer (ET) processes in a single double-stranded DNA (dsDNA) molecule (see figure) reveals that FRET remains almost unaltered in the presence of ET. Present systems also demonstrate the potential for long-range ET studies through the base stack in single dsDNA molecules.

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Atto 520-Biotin, BioReagent, suitable for fluorescence, ≥90% (HPLC)