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93524

Supelco

4-(1-Methylhydrazino)-7-nitrobenzofurazan

for HPLC derivatization, LiChropur™, ≥97.0%

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About This Item

Empirical Formula (Hill Notation):
C7H7N5O3
CAS Number:
214147-22-5
Molecular Weight:
209.16
Beilstein:
8316412
MDL number:
MFCD03453275
UNSPSC Code:
12000000
PubChem Substance ID:
329770247
NACRES:
NA.22

grade

for HPLC derivatization

Quality Level

100

Assay

≥97.0% (HPLC)
≥97.0%

form

powder

quality

LiChropur™

technique(s)

HPLC: suitable

mp

~160 °C

storage temp.

2-8°C

SMILES string

CN(N)c1ccc([N+]([O-])=O)c2nonc12

InChI

1S/C7H7N5O3/c1-11(8)4-2-3-5(12(13)14)7-6(4)9-15-10-7/h2-3H,8H2,1H3

InChI key

GVUXVETWVIWDEV-UHFFFAOYSA-N

Other Notes

Superior reagent for monitoring aldehydes and ketones in air[1][2]; Fluorogenic peroxidase substrate[3]

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBT6421

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4-(N-Methylhydrazino)-7-nitro-2,1,3-benzooxadiazole (MNBDH): A Novel Fluorogenic Peroxidase Substrate The authors would like to thank the Fonds der Chemischen Industrie (Frankfurt/Main) for financial support.
Meyer et al.
Angewandte Chemie (International ed. in English), 39(8), 1453-1455 (2000-04-25)
A Büldt et al.
Analytical chemistry, 71(15), 3003-3007 (1999-08-18)
A selective and versatile fluorescence spectroscopic method for the determination of nitrite in waters has been developed. Nitrite reacts in the presence of mineral acids with the nonfluorescent N-methyl-4-hydrazino-7-nitrobenzofurazan forming N-methyl-4-amino-7-nitrobenzofurazan, which can be detected by fluorescence spectroscopy with an
A Büldt et al.
Analytical chemistry, 71(9), 1893-1898 (1999-05-01)
The synthesis of N-methyl-4-hydrazino-7-nitrobenzofurazan (MNBDH) and its application as a new reagent for the determination of aldehydes and ketones are described. MNBDH reacts with carbonyl compounds in acidic media to the corresponding MNBD-hydrazones. In contrast to the established reagent 2,4-dinitrophenylhydrazine

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