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Benfuracarb

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C20H30N2O5S
CAS Number:
82560-54-1
Molecular Weight:
410.53
MDL number:
MFCD00210247
UNSPSC Code:
41116107
PubChem Substance ID:
329753802
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

format

neat

SMILES string

CCOC(=O)CCN(SN(C)C(=O)Oc1cccc2CC(C)(C)Oc12)C(C)C

InChI

1S/C20H30N2O5S/c1-7-25-17(23)11-12-22(14(2)3)28-21(6)19(24)26-16-10-8-9-15-13-20(4,5)27-18(15)16/h8-10,14H,7,11-13H2,1-6H3

InChI key

FYZBOYWSHKHDMT-UHFFFAOYSA-N

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General description

Benfuracarb belongs to the benzofuranyl methylcarbamate insecticide group of pesticides used to control insect pests in citrus, maize, sugar beet and vegetables.

Application

Benfuracarb may be used as a reference standard for the determination of the analyte:
  • In bananas by application of a modified QuEChERS procedure followed by ultra high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS).
  • In honeybees, honey and bee pollen by liquid chromatography coupled to tandem mass spectrometry.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

H301 + H331,H361f,H410

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

>212.0 °F

Flash Point(C)

> 100 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL1809
BCCJ0073
BCCB7712
BCBW8924
BCBS3726V

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K Ameno et al.
Forensic science international, 116(1), 59-61 (2000-12-19)
We describe four fatal cases due to ingestion of carbofuran, a carbamate insecticide. Carbofuran was detected in the gastric contents using thin layer chromatography (TLC) and gas chromatography/mass spectrophotometry (GC/MS), and quantified in the blood using a gas chromatograph equipped
Maria Rosaria Iesce et al.
Environmental science and pollution research international, 13(2), 105-109 (2006-04-15)
N-methylcarbamate insecticides are widely used chemicals for crop protection. This study examines the hydrolytic and photolytic cleavage of benfuracarb, carbosulfan and carbofuran under natural conditions. Their toxicity and that of the corresponding main degradation products toward aquatic organisms were evaluated.
S Kilani-Morakchi et al.
Communications in agricultural and applied biological sciences, 71(2 Pt B), 555-562 (2007-03-28)
In order to complete previous studies conducted on Blattella germanica, three insecticides from different groups were evaluated: boric acid, an inorganic compound, benfuracarb, a carbamate, and halofenozide, a non-steroidal ecdysone agonist. Boric acid (8.20%, LD50) and benfuracarb (2%, LD50) were
S Ichikawa et al.
The Journal of toxicological sciences, 20(2), 143-148 (1995-05-01)
The antidotal action of atropine sulfate and 2-pyridine aldoxime methiodide (2-PAM) against poisoning attributable to the new procarbamate insecticide benfuracarb [(ethyl N-[2,3-dihydro-2,2-dimethylbenzofuran-7-yloxycarbonyl (methyl) aminothio]-N-isopropyl-beta-alaninate] was compared utilizing rats as our experimental model. Both the intraperitoneal and oral administrations of these
S K Lee et al.
International journal of legal medicine, 112(4), 268-270 (1999-08-05)
We describe here three cases involving acute fatalities due to benfuracarb ingestion and the forensic toxicological implications. Benfuracarb, a carbamate insecticide and its main metabolite carbofuran, were detected using thin layer chromatography (TLC) and gas chromatography/mass spectrophotometry (GC/MS) after extraction
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