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769517

Sigma-Aldrich

Sodium (meta)periodate

≥99%

Synonym(s):

Sodium periodate

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About This Item

Linear Formula:
NaIO4
CAS Number:
7790-28-5
Molecular Weight:
213.89
EC Number:
232-197-6
MDL number:
MFCD00003534
UNSPSC Code:
12352302
PubChem Substance ID:
329767447
NACRES:
NA.23

Quality Level

100

Assay

≥99%
99.0-101.0% (RT)

form

crystalline

anion traces

sulfate (SO42-): ≤0.005%

cation traces

Mn: ≤0.0001%

SMILES string

[Na+].[O-]I(=O)(=O)=O

InChI

1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

InChI key

JQWHASGSAFIOCM-UHFFFAOYSA-M

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Application

Sodium metaperiodate finds application as catalyst in organic reactions]. For example it is known to catalyze selective sulfonylation of aromatics and the graft copolymerization of acrylonitrile.
Useful reagent for the oxidation of carbohydrates prior to labeling with biotin hydrazide

Analysis Note

Chloride, Chlorate, Bromide, Bromate (as Cl) ≤ 0.01 %

Signal Word

Danger

Hazard Statements

H271,H314,H372,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1

Target Organs

thymus gland

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Sodium Periodate Catalyzed Selective Sulfonylation of Aromatics
Bandgar, BP. and Kample, VT.
Chemistry Letters (Jpn), 10, 1066-1067 (2002)
Rout, J., et al.
Journal of Applied Polymer Science, 84, 75-75 (2002)
Sara Nejati et al.
Colloids and surfaces. B, Biointerfaces, 196, 111347-111347 (2020-09-20)
Injectable hydrogels with conductivity are highly desirable as scaffolds for the engineering of various electrical stimuli-responsive tissues, including nerve, muscle, retina, and bone. However, oxygen deprivation within scaffolds can lead to failure by causing cell necrosis. Therefore, an oxygen release
Verónica López Durán et al.
Carbohydrate polymers, 182, 1-7 (2017-12-28)
Despite the different chemical approaches used earlier to increase the ductility of fibre-based materials, it has not been possible to link the chemical modification to their mechanical performance. In this study, cellulose fibres have been modified by periodate oxidation, alone
Panpan Li et al.
Carbohydrate polymers, 199, 219-227 (2018-08-26)
Deep eutectic solvents (DESs) are potential green systems that can be used as reagents, extraction agents and reaction media. DESs are often biodegradable, easy to prepare and have low toxicity. In this work, a recyclable DES formed from aminoguanidine hydrochloride
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