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Sigma-Aldrich

4-Methoxybenzyl carbazate

≥98.0%

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About This Item

Empirical Formula (Hill Notation):
C9H12N2O3
CAS Number:
Molecular Weight:
196.20
Beilstein:
2052164
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

≥98.0%

mp

75-78 °C

SMILES string

COc1ccc(COC(=O)NN)cc1

InChI

1S/C9H12N2O3/c1-13-8-4-2-7(3-5-8)6-14-9(12)11-10/h2-5H,6,10H2,1H3,(H,11,12)

InChI key

JKBMMHKEAGEILO-UHFFFAOYSA-N

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Application

4-Methoxybenzyl carbazate may be used to synthesize 5,10-diiminoporphodimethene (a dearomatized porphyrinoid) and N-(2,4-dihydroxythiobenzoyl)-4-methoxybenzyl carbazate

Other Notes

Starting material for the azide used to introduce the pMZ-amino protection which is removable under mild hydrolytic conditions

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Experimental and Theoretical Characterization of 5, 10-Diminoporphodimethenes: Dearomatized Porphyrinoids from Palladium-Catalyzed Hydrazinations of 5, 10-Diarylporphyrins.
Basic B, et al.
ChemPlusChem, 79(6), 813-824 (2014)
F. Weygand et al.
Chemische Berichte, 95, 1-1 (1962)
C. Ressler et al.
The Journal of Organic Chemistry, 36, 3961-3961 (1971)
H. Yamada et al.
Bulletin of the Chemical Society of Japan, 57, 3333-3333 (1984)
Synthesis and fungistatic activity of new groups of 2, 4-dihydroxythiobenzoyl derivatives against phytopathogenic fungi
Legocki, Jan, et al.
Journal of Agricultural and Food Chemistry, 51.2 , 362-368 (2003)

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