520489
3-Fluorophenylzinc iodide solution
0.5 M in THF
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About This Item
Linear Formula:
FC6H4ZnI
CAS Number:
Molecular Weight:
287.39
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
concentration
0.5 M in THF
density
0.995 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Fc1cccc([Zn]I)c1
InChI
1S/C6H4F.HI.Zn/c7-6-4-2-1-3-5-6;;/h1-2,4-5H;1H;/q;;+1/p-1
InChI key
GRDTUCMQMQTYBS-UHFFFAOYSA-M
Application
3-Fluorophenylzinc iodide can be used as a reagent to prepare arylvinyl indoles via thermolysis of phenyl substituted allenylphenyl azides.[1]
Legal Information
Product of Rieke® Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
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Allenyl azide cycloaddition chemistry. Synthesis of annelated indoles from 2-(allenyl) phenyl azide substrates
Feldman KS, et al.
Organic Letters, 8(14), 3113-3116 (2006)
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