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371963

Sigma-Aldrich

Hexafluoropropene, trimer

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25 G
€101.50

€101.50

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25 G
€101.50

About This Item

Linear Formula:
[CF3C(F)=CF2]3
CAS Number:
6792-31-0
Molecular Weight:
450.07
MDL number:
MFCD00043821
UNSPSC Code:
12352100
PubChem Substance ID:
24863138
NACRES:
NA.22

€101.50

List Price€203.00Save 50%
Please contact Customer Service for Availability
Request a Bulk Order

form

liquid

Quality Level

100

bp

110-115 °C (lit.)

density

1.83 g/mL at 25 °C (lit.)

functional group

fluoro

SMILES string

FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F

InChI

1S/3C3F6/c3*4-1(2(5)6)3(7,8)9

InChI key

VJRSWIKVCUMTFK-UHFFFAOYSA-N

General description

Spectra of three isomeric trimers of hexafluoropropene have been investigated.[1] It reacts with primary amines, via indirect substitution of fluorine atoms, to form the corresponding enamines and enimines.[2]

Application

Hexafluoropropene, trimer may be used in the preparation of photochromic spiroindolinonaphthoxazine derivative.[3] It may be used in the preparation of 2-trifluoromethyl-3-heptadifluoroisopropyl-2-perfluoropentene-4-(N′,N′-dimethylamino propyl) imino(I).[4]

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

75.2 °F - closed cup

Flash Point(C)

24 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBK9975
STBK5530
STBK5036
STBK1970
STBF2489V

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Synthesis and NMR study of 9'-substituted spiroindolinonaphthoxazine derivatives.
Kakishita T, et al.
Journal of Heterocyclic Chemistry, 29(7), 1709-1715 (1992)
Interaction of hexafluoropropene trimers with ammonia and primary amines.
Del'tsova DP, et al.
Journal of Fluorine Chemistry, 79(1), 97-102 (1996)
Non-bond F? F nuclear spin couplings II. Hexafluoropropene trimers.
Cavagna F and Schumann C.
Journal of Magnetic Resonance, 22(2), 333-334 (1969)
Jost Leemhuis et al.
The Journal of pharmacology and experimental therapeutics, 300(3), 1000-1007 (2002-02-28)
The small GTPase RhoA can retract cell extensions by acting on two Rho kinases (ROCKs). Activated protein kinase A (PKA) inhibits RhoA and induces extensions. The isoquinoline H89 inhibits PKA and thus should prevent the inactivation of RhoA. In kinase
D Findik et al.
Journal of cellular biochemistry, 57(1), 12-21 (1995-01-01)
In addition to a role for de novo protein synthesis in apoptosis we have previously shown that activation of a protein phosphatase or loss of activity of a kinase is also important in radiation-induced apoptosis in human cells [Baxter, and
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Questions

  1. Is it mixture of isomers or only one isomer?

    1 answer

    1. Product 371963 is a hexafluoropropene trimer. The potential isomer (hexafluorocyclopropane) content is not determined. So it is a mixture.

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