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226475

Sigma-Aldrich

Phenyl vinyl sulfide

97%

Synonym(s):

(Phenylthio)ethylene

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About This Item

Linear Formula:
C6H5SCH=CH2
CAS Number:
1822-73-7
Molecular Weight:
136.21
Beilstein:
969970
EC Number:
217-351-2
MDL number:
MFCD00009646
UNSPSC Code:
12352100
PubChem Substance ID:
24853571
NACRES:
NA.22

Assay

97%

form

liquid

refractive index

n20/D 1.599 (lit.)

bp

94-95 °C/25 mmHg (lit.)

density

1.042 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C=CSc1ccccc1

InChI

1S/C8H8S/c1-2-9-8-6-4-3-5-7-8/h2-7H,1H2

InChI key

GMPDOIGGGXSAPL-UHFFFAOYSA-N

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Application

Phenyl vinyl sulfide was used in the synthesis of 2-fluoropyridinyl-6-oxy- precursors.

Pictograms

Flame
GHS02

Signal Word

Warning

Hazard Statements

H226

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

114.8 °F - closed cup

Flash Point(C)

46 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Laurent Debien et al.
Organic letters, 15(24), 6250-6253 (2013-11-26)
2-Fluoropyridinyl-6-oxy- precursors derived from phenyl vinyl sulfide react with radicals generated from xanthates via an addition-elimination process to furnish the corresponding vinyl sulfides in good yields. This convergent method is operationally simple and enables a straightforward synthesis of the difficult

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