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204315

Sigma-Aldrich

Selenium dioxide

99.999% trace metals basis

Synonym(s):

NSC 56753, Selenium oxide

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About This Item

Linear Formula:
SeO2
CAS Number:
Molecular Weight:
110.96
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.23

vapor pressure

1 mmHg ( 157 °C)

Assay

99.999% trace metals basis

form

solid

mp

315 °C (subl.) (lit.)

SMILES string

O=[Se]=O

InChI

1S/O2Se/c1-3-2

InChI key

JPJALAQPGMAKDF-UHFFFAOYSA-N

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Application

Mild oxidizing reagent for allylic olefins and acetylenes. Conversion of 1,3-diketones to 1,2,3-triones.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Tetrahedron Letters, 34, 2979-2979 (1993)
Asian Journal of Chemistry, 19, 4107-4107 (2007)
Vijay P Singh et al.
Chemistry, an Asian journal, 6(6), 1431-1442 (2011-05-11)
The syntheses of selenenate/seleninate esters and related derivatives by aromatic nucleophilic substitution (S(N)Ar) reactions of 2-bromo-3-nitrobenzylalcohol (13) and 2-bromo-3-nitrobenzaldehyde (17) with Na(2)Se(2)/nBuSeNa are described. The reaction of 13 with Na(2)Se(2) at room temperature afforded 7-nitro-1,2-benzisoselenole(3H) (15) instead of the desired
Imed Messaoudi et al.
Experimental and toxicologic pathology : official journal of the Gesellschaft fur Toxikologische Pathologie, 62(3), 281-288 (2009-05-26)
The aim of this study was to evaluate the potential benefit of combined treatment with zinc (Zn) and selenium (Se) in reversing cadmium (Cd)-induced oxidative stress in erythrocytes, compared to Se or Zn treatment alone in rats exposed to Cd.
Zhangrong Lou et al.
Chemical communications (Cambridge, England), 49(24), 2445-2447 (2013-02-19)
Based on a novel strategy for modulating the fluorescence of selenide and selenoxide, we have designed and developed a reversible fluorescent probe for hypochloric acid. And the synthesis, characterization, fluorescence properties, as well as the biological applications in living cells

Articles

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

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