404985
Titanium(IV) chloride solution
0.09 M in 20% HCl
Synonym(s):
Titanium tetrachloride
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About This Item
Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.21
form:
liquid
Recommended Products
form
liquid
Quality Level
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.09 M in 20% HCl
density
1.099 g/mL at 25 °C
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
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Application
Reagent for the detection of peroxides in ethyl ether. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Titanium(IV) chloride (TiCl4) solution may be used to synthesize nanosized titanium dioxide and nano/micro-sized titania powders.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Titanium tetrachloride promoted hydrolysis of cephalosporin tert-butyl esters.
Valencic M, et al.
Tetrahedron Letters, 39(12), 1625-1628 (1998)
Mechanism of enhanced performance of dye-sensitized solar cell based TiO2 films treated by titanium tetrachloride.
Long-Yue Z, et al.
Chinese Physics Letters, 21(9), 1835-1835 (2004)
Reagent Chemicals (1992)
Influence of solution concentration on the hydrothermal preparation of titania crystallites.
Yanqing Z, et al.
Journal of Materials Chemistry, 11(5), 1547-1551 (2001)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
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