572543
Woollins′ Reagent
Synonym(s):
2,4-Diphenyl-1,3-diselenadiphosphetane 2,4-diselenide
About This Item
Recommended Products
form
solid
Quality Level
mp
206-210 °C (lit.)
storage temp.
2-8°C
SMILES string
[Se]=P1([Se]P(=[Se])([Se]1)c2ccccc2)c3ccccc3
InChI
1S/C12H10P2Se4/c15-13(11-7-3-1-4-8-11)17-14(16,18-13)12-9-5-2-6-10-12/h1-10H
InChI key
GKYFQRQKPYPLGJ-UHFFFAOYSA-N
Application
- Benzoic hydrazides to yield spiro heterocycles
- Secondary amines
- Aromatic diols to yield 10-membered phosphorus-selenium heterocycles
Reagent involved in ring-opening, deselenation and phosphorus-phosphorus coupling
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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