525693
6-Bromo-2-pyridinecarboxaldehyde
97%
Synonym(s):
2-Bromo-6-formylpyridine, 2-Bromopyridine-6-carboxaldehyde, 2-Bromopyridyl-6-carboxaldehyde, 2-Formyl-6-bromopyridine, 6-Bromo-2-formylpyridine, 6-Bromo-2-pyridinecarbaldehyde, 6-Bromopicolinaldehyde, 6-Bromopyridine-2-aldehyde
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About This Item
Empirical Formula (Hill Notation):
C6H4BrNO
CAS Number:
Molecular Weight:
186.01
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
mp
81-85 °C (lit.)
functional group
aldehyde
bromo
storage temp.
2-8°C
SMILES string
[H]C(=O)c1cccc(Br)n1
InChI
1S/C6H4BrNO/c7-6-3-1-2-5(4-9)8-6/h1-4H
InChI key
QWFHFNGMCPMOCD-UHFFFAOYSA-N
General description
6-Bromo-2-pyridinecarboxaldehyde is a pyridine derivative. It participates in the synthesis of meso-substituted trans-A2B2-porphyrin.
Application
6-Bromo-2-pyridinecarboxaldehyde may be used in the synthesis of:
- 6-([2,2′-bi(1,3-dithiolylidene)]-4-yl)picolinaldehyde
- tris(2-pyridylmethyl)amine (Tpy) derivative having Tpy core bearing a 3-formyl-phenyl substituent on one of the three arms
- syn- and anti- forms of 4-(6-bromopyridin-2-yl)-3-methyl-3-phenyloxetan-2-one
- 6-(2,4,6-triisopropylphenyl)-2-pyridinecarboxaldehyde
Substrate used in a study of a rhodium-catalyzed, reductive aldol coupling with divinyl ketones leading to syn ß-hydroxyenones.
Useful building block for Tris[(pyridyl)methyl]amine ligands.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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