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Sigma-Aldrich

Manganese(0) carbonyl

98%

Synonym(s):

Decacarbonyl dimanganese(0), Dimanganese(0) decacarbonyl

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About This Item

Linear Formula:
Mn2(CO)10
CAS Number:
10170-69-1
Molecular Weight:
389.98
EC Number:
233-445-6
MDL number:
MFCD00011115
UNSPSC Code:
12352103
PubChem Substance ID:
24854511
NACRES:
NA.23

Quality Level

100

Assay

98%

form

powder or crystals

reaction suitability

core: manganese
reagent type: catalyst

mp

154 °C (lit.)

storage temp.

2-8°C

SMILES string

[Mn].[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/10CO.2Mn/c10*1-2;;

InChI key

QFEOTYVTTQCYAZ-UHFFFAOYSA-N

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General description

Manganese(0) carbonyl, also known as Decacarbonyl dimanganese exhibits interesting electrochemicalproperties owing to the presence of carbonyl ligands and the manganese metalcenters. In electrochemistry, this compound can act as a carbonyl source andpotentially participate in redox reactions.

Application

Manganese(0) carbonyl can be used:
  • As a precursor to prepare Ni2–xMnxP nanoparticles to fabricate a catalyst for electrochemical oxygen evolution reaction(OER).
  • To fabricate an ultra-sensitive manganese doped MoS2 electrochemical dopamine sensor via modified chemical vapor deposition(CVD) method.
  • As a reducing agent to synthesize Pt-Co electrocatalyst for oxygen reduction reactions in fuel cells. Mn and CO atoms produced during decomposition acts as reducing and surface structure guiding agents respectively.

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H331

Hazard Classifications

Acute Tox. 3 Inhalation

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Doping and decorating 2D materials for biosensing: benefits and drawbacks
Hui Ling Chia, et al.
Advanced Functional Materials , 31, 2102555-2102555 (2021)
Pt-Co Electrocatalysts: Syntheses, Morphologies, and Applications
Hao Chen, et al.
Small, 18, 2204100-2204100 (2022)
Ni2?xMnxP Nanoparticles as Earth-Abundant Precatalysts for Electrochemical Water Oxidation
Fatemeh Aghabozorgi, et al
Chemistry of Materials, 36, 2461-2472 (2024)

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