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60238

Sigma-Aldrich

Potassium fluoride

BioUltra, ≥99.5% (F)

Synonym(s):

KF

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About This Item

Linear Formula:
KF
CAS Number:
7789-23-3
Molecular Weight:
58.10
Beilstein:
3902818
MDL number:
MFCD00011398
UNSPSC Code:
12352302
PubChem Substance ID:
57651737
NACRES:
NA.25

product line

BioUltra

Assay

≥99.5% (F)

form

solid

impurities

insoluble matter, passes filter test
≤0.01% free acid (as HF)
≤0.01% free alkali (as KOH)
≤0.1% potassium fluoro silicate (K2SiF6)

pH

7.0-8.5 (25 °C, 1 M in H2O)

mp

858 °C (lit.)

solubility

H2O: 1 M at 20 °C, clear, colorless

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤100 mg/kg

cation traces

Al: ≤5 mg/kg
As: ≤3 mg/kg
Ba: ≤5 mg/kg
Bi: ≤5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
Li: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Mo: ≤5 mg/kg
Na: ≤2000 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Sr: ≤5 mg/kg
Zn: ≤5 mg/kg

λ

1 M in H2O

UV absorption

λ: 260 nm Amax: 0.01
λ: 280 nm Amax: 0.01

SMILES string

[F-].[K+]

InChI

1S/FH.K/h1H;/q;+1/p-1

InChI key

NROKBHXJSPEDAR-UHFFFAOYSA-M

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Application

Potassium fluoride may be used in thermodynamic analysis of DNA-ligand binding and studies on the structural stability of proteins and peptides.
A versatile fluoride ion source used in a study of ion-specific swelling and de-swelling of ampholytic polymer gels, in the room temperature oxidation of noble metals in HF, and in the measurement of electronic polarizabilities of ions in polymers of alkali halides.

Other Notes

Inhibitor of pyrophosphatase, hence prevents loss of ATP by hydrolytic cleavage of the pyrophosphate bond in the assay of amidophosphoribosyltransferase; Strongly inhibits polypeptide chain initiation in the reticulocyte lysate cell-free system

Pictograms

CorrosionSkull and crossbones
GHS05,GHS06

Signal Word

Danger

Hazard Statements

H301 + H311 + H331 - H318

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J C O'Rourke et al.
The Journal of biological chemistry, 250(9), 3443-3450 (1975-05-20)
KF (30 mM) strongly inhibits polypeptide chain initiation in the reticulocyte lysate cell-free system.. Chain elongation is partially inhibited but proceeds to a significant extent with little initiation of new chains. Polysome breakdown is incomplete after incubations as long as
Amidophosphoribosyltransferase (chicken liver).
J M Lewis et al.
Methods in enzymology, 51, 171-178 (1978-01-01)
Lirong Wen et al.
Journal of combinatorial chemistry, 11(5), 799-805 (2009-07-28)
A series of new functionalized thiochromeno[2,3-b]pyridine derivatives have been synthesized via a sequence of Knoevenagel condensation, Michael addition, cyclization, and intramolecular nucleophilic substitution, which is first catalyzed by KF/neutral Al(2)O(3) cooperated with PEG 6000 under microwave irradiation. Experimental results indicated
E Gershonov et al.
The Journal of organic chemistry, 74(1), 329-338 (2008-12-05)
A facile solvent-free hydrolysis (chemical destruction) of the warfare agents VX (O-ethyl S-2-(diisopropylamino)ethyl methylphosphonothioate), GB (O-isopropyl methylphosphonofluoridate or sarin), and HD (2,2'-dichloroethyl sulfide or sulfur mustard) upon reaction with various solid-supported fluoride reagents is described. These solid reagents include different
Mónica Calvo-Polanco et al.
Physiologia plantarum, 135(1), 51-61 (2009-01-06)
Black spruce (Picea mariana), white spruce (Picea glauca) and jack pine (Pinus banksiana) were inoculated with Suillus tomentosus and subjected to potassium fluoride (1 mM KF and 5 mM KF) in the presence and absence of 60 mM NaCl. The
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