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Flubendiamide

PESTANAL®, analytical standard

Synonym(s):

N2-[1,1-Dimethyl-2-(methylsulfonyl)ethyl]-3-iodo-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}-1,2-benzenedicarboxamide

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About This Item

Empirical Formula (Hill Notation):
C23H22F7IN2O4S
CAS Number:
272451-65-7
Molecular Weight:
682.39
Beilstein:
11326832
MDL number:
MFCD09953911
UNSPSC Code:
41116107
PubChem Substance ID:
329754332
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

Cc1cc(ccc1NC(=O)c2cccc(I)c2C(=O)NC(C)(C)CS(C)(=O)=O)C(F)(C(F)(F)F)C(F)(F)F

InChI

1S/C23H22F7IN2O4S/c1-12-10-13(21(24,22(25,26)27)23(28,29)30)8-9-16(12)32-18(34)14-6-5-7-15(31)17(14)19(35)33-20(2,3)11-38(4,36)37/h5-10H,11H2,1-4H3,(H,32,34)(H,33,35)

InChI key

ZGNITFSDLCMLGI-UHFFFAOYSA-N

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General description

Flubendiamide is a novel insecticide that is grouped under the family of phthalic acid diamides. It is largely used against lepidopteron pests in various annual and perennial crops.

Application

Flubendiamide may be used as an analytical reference standard for the determination of the analyte in vegetables and fruits by high performance liquid chromatography coupled to ultraviolet detector (HPLC-UV) and HPLC combined with tandem mass spectrometry (MS/MS), respectively.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK1411
BCCD9411
BCCB3523
BCBT5010
SZBE216XV

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A fast method for determination of flubendiamide in vegetables by liquid chromatography.
Mukherjee I, et al.
Pesticide Research Journal, 24(2), 159-162 (2012)
Simple and efficient method for the estimation of residues of flubendiamide and its metabolite desiodo flubendiamide.
Singh B, et al.
Journal of Agricultural and Food Chemistry, 56(7), 2299-2302 (2008)
Shaon Kumar Das et al.
Bulletin of environmental contamination and toxicology, 105(2), 261-269 (2020-07-16)
Persistence and sorption behaviour of flubendiamide in two different Indian soils as affected by maize stalk biochar was studied. The persistence was more in West Bengal soil (178.6 days) than Sikkim soil (165.3 days) at 10 µg g-1 fortification level. Biochar
Rajesh Mandil et al.
Chemico-biological interactions, 260, 91-101 (2016-11-09)
Study was undertaken to evaluate ameliorative potential of α-tocopherol against copper sulphate and flubendiamide alone and in combination-induced toxicity in rats following 90 days exposure. Absolute and relative organ weights did not differ between treatments groups. Increase of LPO in
Ana M Ares et al.
Food chemistry, 232, 169-176 (2017-05-12)
In this study, a new method has been developed to determine flubendiamide in honey using liquid chromatography coupled to a selective mass spectrometry detector (quadrupole-time-of-flight). An efficient sample treatment involving a solid phase extraction with a C
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