If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
1.06329
Sodium hydrogen carbonate
for analysis EMSURE® ACS,Reag.Ph Eur
Synonym(s):
Sodium bicarbonate
About This Item
99.7-100.3% dry basis (acidimetric)
Recommended Products
grade
ACS reagent
Quality Level
Agency
reag. Ph. Eur.
product line
EMSURE®
Assay
99.0-101.0% (acidimetric)
99.7-100.3% dry basis (acidimetric)
form
powder
potency
4220 mg/kg LD50, oral (Rat)
impurities
≤0.0065% Iodine reducing matter (as I)
≤0.015% Insoluble matter
loss
≤0.2% loss on drying, Silica gel
pH
8.6 (20 °C, 50 g/L in H2O)
pKa (25 °C)
(1) 6.37, (2) 10.25 (carbonic acid)
mp
270 °C (decomposition)
solubility
96 g/L
density
2.22 g/cm3 at 20 °C
2.16 g/mL at 25 °C (lit.)
bulk density
1000 kg/m3
anion traces
chloride (Cl-): ≤0.002%
phosphate (PO43-): ≤0.001%
phosphate, silicate (as SiO2): ≤0.005%
sulfate (SO42-): ≤0.015%
sulfur compounds (as SO42-): ≤0.003%
cation traces
As: ≤0.0002%
Ca: ≤0.01%
Cu: ≤0.0002%
Fe: ≤0.0005%
K: ≤0.005%
Mg: ≤0.005%
N: ≤0.0005%
NH4+: ≤0.0005%
Pb: ≤0.0005%
heavy metals (as Pb): ≤0.0005%
storage temp.
2-30°C
SMILES string
[Na+].OC([O-])=O
InChI
1S/CH2O3.Na/c2-1(3)4;/h(H2,2,3,4);/q;+1/p-1
InChI key
UIIMBOGNXHQVGW-UHFFFAOYSA-M
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Analysis Note
Identity: passes test
Assay (acidimetric; calculated on dried substance): 99.7 - 100.3 %
Assay (acidimetric): 99.0 - 101.0 %
Insoluble matter: ≤ 0.015 %
pH-value (5 %; water): ≤ 8.6
Chloride (Cl): ≤ 0.002 %
Phosphate (PO₄): ≤ 0.001 %
Sulfate (SO₄): ≤ 0.015 %
Phosphate and Silicate (as SiO₂): ≤ 0.005 %
Sulfur compounds (as SO₄): ≤ 0.003 %
Total nitrogen (N): ≤ 0.0005 %
Ammonium (NH₄): ≤ 0.0005 %
Heavy metals (as Pb): ≤ 0.0005 %
As (Arsenic): ≤ 0.0002 %
Ca (Calcium): ≤ 0.01 %
Cu (Copper): ≤ 0.0002 %
Fe (Iron): ≤ 0.0005 %
K (Potassium): ≤ 0.005 %
Mg (Magnesium): ≤ 0.005 %
Pb (Lead): ≤ 0.0005 %
Iodine reducing matter (as I): ≤ 0.0065 %
Loss on drying (Silica gel): ≤ 0.20 %
Corresponds to ACS, Reag. Ph Eur
Legal Information
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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