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413658

Sigma-Aldrich

Indium(I) iodide

AnhydroBeads™, −10 mesh, 99.999% trace metals basis

Synonym(s):

Indium monoiodide

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About This Item

Linear Formula:
InI
CAS Number:
13966-94-4
Molecular Weight:
241.72
EC Number:
237-746-3
MDL number:
MFCD00135543
UNSPSC Code:
12352302
PubChem Substance ID:
24865876
NACRES:
NA.23

product line

AnhydroBeads™

Assay

99.999% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: indium

impurities

≤15.0 ppm Trace Metal Analysis

particle size

−10 mesh

SMILES string

[In]I

InChI

1S/HI.In/h1H;/q;+1/p-1

InChI key

FOVZCYAIUZHXGB-UHFFFAOYSA-M

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Application

Has been discovered and used as a reagent to propagate some organic reactions, such as cyclization and cleavage of diselenide or disulfide. Can also be used to prepare In-containing complexes.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

accessory

Product No.
Description
Pricing

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Statements

H302,H315,H319,H334,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Tiwari, P.; et al.
Tetrahedron Letters, 47 (14), 2345-2348 (2006)
Brindaban C Ranu et al.
The Journal of organic chemistry, 71(1), 423-425 (2006-01-04)
[reaction: see text] Diphenyl diselenide (and disulfide) undergo facile reaction with indium(I) iodide and the corresponding intermediate complex condenses in situ with a variety of substituted vinyl bromides in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) [Pd(PPh3)4] in THF
Ranu, B.C.; et al.
Tetrahedron Letters, 47 (17), 2859-2861 (2006)
Wuping Liao et al.
Inorganic chemistry, 45(10), 3828-3830 (2006-05-09)
A different thermal treatment of identical reactants (EuI2, NaCN, NaN3, and InI) leads to the formation of the three title compounds. In(0.08)Eu4(NCN)3I3 is isotypic with the reported LiEu4(NCN)3I3, Eu8I9(CN)(NCN)3 represents the first mixed cyanide-cyanamide rare-earth compound, and In(0.28)Eu12(NCN)5I(14.91) is characterized
Goeta, A.; et al.
Tetrahedron, 62, 3582-3599 (2006)

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