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Sigma-Aldrich

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride

≥95.0%

Synonym(s):

5-Norbornene-2,3-dicarboxylic anhydride

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About This Item

Empirical Formula (Hill Notation):
C9H8O3
CAS Number:
826-62-0
Molecular Weight:
164.16
Beilstein:
150228
EC Number:
212-557-9
MDL number:
MFCD00151106
UNSPSC Code:
12352100
PubChem Substance ID:
57647148
NACRES:
NA.22

Assay

≥95.0%

solubility

diethyl ether: 0.1 g/10 mL, clear, colorless

SMILES string

O=C1OC(=O)[C@H]2[C@@H]3C[C@@H](C=C3)[C@@H]12

InChI

1S/C9H8O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h1-2,4-7H,3H2/t4-,5+,6-,7+

InChI key

KNDQHSIWLOJIGP-UMRXKNAASA-N

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General description

Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride reacts with methyl aminomethyllambertianate to give amide of bicyclo[2.2.1]heptan-1,2-dicarbocylic acid with a labdanoid substituent.

Application

  • Sustainable chemical processes with Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride: Research by Kharitonov et al. (2012) explores synthetic transformations of higher terpenoids, employing Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. Their work focuses on creating new cytotoxic agents, contributing to sustainable methodologies in organic synthesis (Kharitonov et al., 2012).
  • Organic synthesis intermediate: Birchall et al. (2021) present a study on Himic Anhydride, utilizing a retro Diels-Alder reaction to demonstrate the application of Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride in teaching advanced organic laboratory techniques. This work includes an accompanying NMR study to further support the educational aspect of organic synthesis (Birchall et al., 2021).

Pictograms

Health hazardCorrosion
GHS08,GHS05

Signal Word

Danger

Hazard Statements

H317,H318,H334

Hazard Classifications

Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Richard Reece et al.
ACS applied materials & interfaces, 12(23), 25683-25692 (2020-05-15)
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An Yang et al.
Dental materials journal, 36(5), 560-565 (2017-06-02)
The aim of the study was to evaluate the effect of modifying polymethyl methacrylate (PMMA) denture base material with polyimide (PI) on its flexural property and biocompatibility. Low molecular weight (1,500 g/mol) PI was synthesized and small amount of PI
Iu V Kharitonov et al.
Bioorganicheskaia khimiia, 38(1), 127-136 (2012-07-17)
Condensation of methyl 16-aminomethyllambertianate with N-Boc-omega-amino acids leads smoothly to 16-(N-Boc-aminononan)- and 16-(N-Boc-aminoundecan)amidomethyllabdanoids. The amide of bicyclo[2.2.1]heptan-1,2-dicarbocylic acid with a labdanoid substituent was obtained under the reaction of methyl aminomethyllambertianate with bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. Intereaction of methyl 16-aminomethyllambertianate with chloroacetyl chloride
R Padhma Priya et al.
Journal of nanoscience and nanotechnology, 15(9), 6739-6746 (2015-12-31)
A new type of siloxane core modified phthalide cardo chain based polyimide (PI) was successfully prepared from siloxane core dianhydride and ether linked phenolphthalein diamine moiety. This PI was further modified with different weight percentages of multi-walled carbon nanotubes (MWCNTs)

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