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83934

Sigma-Aldrich

Tris[3-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)phenyl]phosphine

technical, ≥95% (GCF)

Synonym(s):

Tris[3-(1H,1H,2H,2H-perfluorodecyl)phenyl]phosphine

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About This Item

Empirical Formula (Hill Notation):
C48H24F51P
CAS Number:
Molecular Weight:
1600.60
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:

grade

technical

Assay

≥95% (GCF)

impurities

~5% phospinoxide (31P-NMR)

mp

90-100 °C

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCc1cccc(c1)P(c2cccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c2)c3cccc(CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c3

Other Notes

Phosphine ligand for preparing the Bannwarth catalyst (catalyst for Stille and Suzuki coupling)

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Helvetica Chimica Acta, 84, 735-735 (2001)
S. Schneider et al.
Angewandte Chemie (International Edition in English), 112, 4293-4293 (2000)

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