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710733

Sigma-Aldrich

2,2,5-Trimethyl-4-phenyl-3-azahexane-3-nitroxide

Synonym(s):

1,1-Dimethylethyl-2-methyl-1-phenylpropyl nitroxide, tert-Butyl 1-phenyl-2-methylpropyl nitroxide, NMP universal alkoxyamine nitroxide

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About This Item

Empirical Formula (Hill Notation):
C14H22NO
CAS Number:
61015-94-9
Molecular Weight:
220.33
MDL number:
MFCD16621409
UNSPSC Code:
12162002
PubChem Substance ID:
329763005

refractive index

n20/D 1.515

density

0.953 g/mL at 25 °C

storage temp.

−20°C

SMILES string

CC(C)C(N([O])C(C)(C)C)c1ccccc1

InChI

1S/C14H22NO/c1-11(2)13(15(16)14(3,4)5)12-9-7-6-8-10-12/h6-11,13H,1-5H3

InChI key

VGHCMXLEZFMZOZ-UHFFFAOYSA-N

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Application

Block Copolymer Synthesis Using a Commercially Available NMP Inititator
Stable nitroxide radical useful in controlling living radical polymerizations

Pictograms

Flame over circleSkull and crossbones
GHS03,GHS06

Signal Word

Danger

Hazard Statements

H272,H301

Precautionary Statements

P210 - P301 + P310 + P330

Hazard Classifications

Acute Tox. 3 Oral - Ox. Liq. 3

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

205.0 °F - closed cup

Flash Point(C)

96.1 °C - closed cup

Certificates of Analysis (COA)

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Articles

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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