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673269

Sigma-Aldrich

Sodium dimethylphenylsilanolate hydrate

97%

Synonym(s):

Phenyl(dimethyl)silanolate sodium salt

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About This Item

Linear Formula:
(C6H5)Si(ONa)(CH3)2 · xH2O
Molecular Weight:
174.25 (anhydrous basis)
MDL number:
MFCD08457664
UNSPSC Code:
12352103
PubChem Substance ID:
24885151
NACRES:
NA.22

Assay

97%

form

solid

mp

197-218 °C

SMILES string

[Na+].[H]O[H].C[Si](C)([O-])c1ccccc1

InChI

1S/C8H11OSi.Na.H2O/c1-10(2,9)8-6-4-3-5-7-8;;/h3-7H,1-2H3;;1H2/q-1;+1;

InChI key

GTSOGRDRMFDZQL-UHFFFAOYSA-N

Application

A useful silicon nucleophile for Pd-catalyzed cross-coupling.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)

Articles

Organosilanols

Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.

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