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538639

Sigma-Aldrich

N,N-Dimethyldecylamine

≥90%

Synonym(s):

1-(Dimethylamino)decane

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About This Item

Linear Formula:
CH3(CH2)9N(CH3)2
CAS Number:
1120-24-7
Molecular Weight:
185.35
Beilstein:
1738198
EC Number:
214-302-7
MDL number:
MFCD00015060
UNSPSC Code:
12352100
PubChem Substance ID:
24878348
NACRES:
NA.22

Assay

≥90%

refractive index

n20/D 1.431 (lit.)

bp

234 °C (lit.)

density

0.778 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCN(C)C

InChI

1S/C12H27N/c1-4-5-6-7-8-9-10-11-12-13(2)3/h4-12H2,1-3H3

InChI key

YWWNNLPSZSEZNZ-UHFFFAOYSA-N

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General description

N,N-Dimethyldecylamine is a tertiary amine. It can be prepared by reacting N,N-dimethyldodecylamine, t-butyl hydroperoxide, vanadium oxyacetylacetonate and t-butyl alcohol.

Application

N,N-Dimethyldecylamine may be used as one of the reaction components in the preparation of:
  • comb-shaped quaternized poly(2,6-dimethylphenylene oxide) (PPO)
  • pore-expanded MCM-41 silica
  • QA C10 stationary phase bearing quaternary ammonium embedded between a propyl and a decyl chain

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315

Hazard Classifications

Acute Tox. 4 Oral - Skin Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

197.6 °F - closed cup

Flash Point(C)

92 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Hydroperoxide oxidations catalyzed by metals. II. Oxidation of tertiary amines to amine oxides.
Sheng MN and Zajacek JG.
The Journal of Organic Chemistry, 33(2), 588-590 (1968)
Qiaoxia Liu et al.
Journal of separation science, 35(20), 2685-2692 (2012-09-26)
A stationary phase (named QA C10) with quaternary ammonium embedded between a propyl and a decyl chain was synthesized by immobilization of N,N-dimethyldecylamine on chloropropyl-silica surface. A set of representative neutral, basic, and acidic compounds was employed to evaluate its
Applications of pore-expanded MCM-41 silica: 4. Synthesis of a highly active base catalyst.
Das DD, et al.
Catalysis Communications, 8(5), 829-833 (2007)
Nanwen Li et al.
Journal of the American Chemical Society, 135(27), 10124-10133 (2013-06-01)
To produce an anion-conductive and durable polymer electrolyte for alkaline fuel cell applications, a series of quaternized poly(2,6-dimethyl phenylene oxide)s containing long alkyl side chains pendant to the nitrogen-centered cation were synthesized using a Menshutkin reaction to form comb-shaped structures.
Daria Szymaniak et al.
ChemPlusChem, 85(10), 2281-2289 (2020-09-23)
The synthesis and characteristics are presented of novel double-salt herbicidal ionic liquids (DSHILs) that contain 4-chloro-2-methylphenoxyacetate and trans-cinnamate anions. In the designed synthesis, an anion of natural origin and a herbicidal anion were combined with an amphiphilic bisammonium cation to

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