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512516

Sigma-Aldrich

Chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)

97%

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About This Item

Empirical Formula (Hill Notation):
C23H20ClNiP
CAS Number:
31904-79-7
Molecular Weight:
421.53
MDL number:
MFCD02093655
UNSPSC Code:
12161600
PubChem Substance ID:
24873638
NACRES:
NA.22

Assay

97%

reaction suitability

core: nickel
reagent type: catalyst

mp

175 °C (dec.) (lit.)

SMILES string

Cl[Ni].[CH]1[CH][CH][CH][CH]1.c2ccc(cc2)P(c3ccccc3)c4ccccc4

InChI

1S/C18H15P.C5H5.ClH.Ni/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-5-3-1;;/h1-15H;1-5H;1H;/q;;;+1/p-1

InChI key

PMWXBCDXVGNPAN-UHFFFAOYSA-M

Application

Reactant for synthesis of:
  • Nickel alkynyl and allenylidene complexes
  • Organometallic complexes for nonlinear optics

Reactant for insertion of decamethylsilicocene in nickel-choline bonds

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302 + H312 + H332

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL7083
MKCJ6460
16901CU

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