380415
Trimethyl(phenoxy)silane
97%
Synonym(s):
Phenoxy(trimethyl)silane, Phenyl trimethylsilyl ether
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About This Item
Linear Formula:
C6H5OSi(CH3)3
CAS Number:
Molecular Weight:
166.29
Beilstein:
1905943
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
form:
liquid
Assay:
97%
Recommended Products
Assay
97%
form
liquid
density
0.92 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(C)Oc1ccccc1
InChI
1S/C9H14OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h4-8H,1-3H3
InChI key
OJAJJFGMKAZGRZ-UHFFFAOYSA-N
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General description
Trimethyl(phenoxy)silane is a trimethylsilyl protected alcohol. Direct lateral zincation (DlZn) of trimethyl(phenoxy)silane has been reported. Dielectric studies of phenoxysilane-phenol binary systems has been reported.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
105.8 °F - closed cup
Flash Point(C)
41 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Trimethylsilyl Protection of Alcohols Over Phosphorus Pentoxide Supported on Silica Gel.
Shaterian HR, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 186(7), 1604-1611 (2011)
Eva Hevia et al.
Chemical communications (Cambridge, England), (22)(22), 3240-3242 (2009-07-10)
A new application of zincate [(THF)Li(TMP)(tBu)Zn(tBu)] (1) in alkali-metal mediated zincation (AMMZn) is reported by isolating and structurally defining the first intermediates of direct lateral zincation (DlZn) of trimethyl(phenoxy)silane (2) both of which adopt novel six-element {ZnCSiOLiN} ring structures.
STUDIES ON ALCOXYSILANE-ALCOHOL AND PHENOXYSILANE-PHENOL BINARY SYSTEMS.
Nagy J, et al.
Chemical Engineering Journal, 15(3), 155-167 (1971)
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