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337773

Sigma-Aldrich

Chlorodiisopropylphosphine

96%

Synonym(s):

Diisopropylphosphine chloride

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About This Item

Linear Formula:
[(CH3)2CH]2PCl
CAS Number:
40244-90-4
Molecular Weight:
152.60
MDL number:
MFCD00015027
UNSPSC Code:
12352001
PubChem Substance ID:
24860498
NACRES:
NA.22

Assay

96%

form

liquid

reaction suitability

reagent type: ligand
reaction type: Arylations

refractive index

n20/D 1.475 (lit.)

bp

69 °C/33 mmHg (lit.)

density

0.959 g/mL at 25 °C (lit.)

functional group

phosphine

SMILES string

CC(C)P(Cl)C(C)C

InChI

1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3

InChI key

JZPDBTOWHLZQFC-UHFFFAOYSA-N

Application

Chlorodiisopropylphosphine can be used:
  • To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
  • As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
  • A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H225,H314

Hazard Classifications

Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

39.2 °F - closed cup

Flash Point(C)

4 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis, characterization and use of reactive polymers with diisopropylphenylphosphine groups.
Licea-Claverie A, et al.
Polymer Bull., 39(5), 551-557 (1997)
Metallophosphination of alkynes: efficient synthesis of ?-functionalized alkenylphosphines.
Xi C, et al.
Organometallics, 26(4), 1084-1088 (2007)
A luminescent Pt-POCN pincer complex via direct cyclometalation.
Lavelle K B, et al.
Journal of Organometallic Chemistry, 785, 100-105 (2015)

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