330094

Palladium hydroxide on carbon

extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support

• Synonym(s): Pearlman’s catalyst
• Empirical Formula (Hill Notation): H₂O₂Pd
• CAS Number: 12135-22-7
• Molecular Weight: 140.43
• EC Number: 235-219-2
• MDL number: MFCD00064599
• UNSPSC Code: 12161600
• PubChem Substance ID: 24859831
• NACRES: NA.22

Properties

• form: powder
• contains: ~50% water
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• extent of labeling: 20 wt. % loading (dry basis)
• weight: Unit weight excludes weight of water
• matrix: carbon, wet support
• SMILES string: O[Pd]O
• InChI: 1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
• InChI key: NXJCBFBQEVOTOW-UHFFFAOYSA-L

Description

Application

Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.

Useful reagent for debenzylation.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves