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308617

Sigma-Aldrich

tert-Butyltrichlorosilane

96%

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About This Item

Linear Formula:
(CH3)3CSiCl3
CAS Number:
18171-74-9
Molecular Weight:
191.56
Beilstein:
1736174
EC Number:
242-059-7
MDL number:
MFCD00000480
UNSPSC Code:
12352103
PubChem Substance ID:
24858681
NACRES:
NA.23
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Assay

96%

form

solid

bp

132-134 °C (lit.)

mp

97-100 °C (lit.)

SMILES string

CC(C)(C)[Si](Cl)(Cl)Cl

InChI

1S/C4H9Cl3Si/c1-4(2,3)8(5,6)7/h1-3H3

InChI key

MOOUPSHQAMJMSL-UHFFFAOYSA-N

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General description

tert-Butyltrichlorosilane is a tert-alkyltrichlorosilane that can be prepared by reacting trimethyl chloride and silicon tetrachloride. It can be used in the synthesis of tert-butyl silsequioxanes by hydrolytic condensation in DMSO.[1][2]

Application

Hydrolytic condensation of tert-butyltrichlorosilane (tBuSiCl3)in DMSO and water was investigated. The process results in the formation of tBu2Si2O(OH)4, the Ti complex of the intermediate produce active heterogeneous epoxidation catalysts.[3]

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H228,H314

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

104.0 °F - closed cup

Flash Point(C)

40 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBG0391V
SHBD4795V
SHBC2640V
17822BF
14006PO

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Silsesquioxane-Based Homogeneous and Heterogeneous Epoxidation Catalysts Developed by Using High-Speed Experimentation
Pescarmona PP, et al.
Chemistry?A European Journal , 10(7), 1657-1665 (2004)
Silsesquioxane-Based Homogeneous and Heterogeneous Epoxidation Catalysts Developed by Using High-Speed Experimentation,
Pescarmona PP, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 116 (38), 20433-20437 (2012)
Organomagnesium synthesis of sec-butyl-and tert-alkylchlorogermanes and their reaction with ethynylmagnesium bromide
Yarosh OG, et al.
Russ. J. Gen. Chem., 75(5), 714-718 (2005)

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