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Sigma-Aldrich

2,6-Bis(4-azidobenzylidene)-4-methylcyclohexanone

contains 20-45% water as stabilizer, 97%

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About This Item

Empirical Formula (Hill Notation):
C21H18N6O
CAS Number:
5284-79-7
Molecular Weight:
370.41
Beilstein:
3017027
MDL number:
MFCD00011665
UNSPSC Code:
12352100
PubChem Substance ID:
24856859

Assay

97%

contains

20-45% water as stabilizer

reaction suitability

reaction type: click chemistry

mp

124-126 °C (lit.)

storage temp.

2-8°C

SMILES string

CC1CC(=C/c2ccc(cc2)N=[N+]=[N-])\C(=O)\C(C1)=C\c3ccc(cc3)N=[N+]=[N-]

InChI

1S/C21H18N6O/c1-14-10-17(12-15-2-6-19(7-3-15)24-26-22)21(28)18(11-14)13-16-4-8-20(9-5-16)25-27-23/h2-9,12-14H,10-11H2,1H3/b17-12+,18-13+

InChI key

MLIWQXBKMZNZNF-PWDIZTEBSA-N

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Application

2,6-Bis(4-azidobenzylidene)-4-methylcyclohexanone has been used:
  • in the preparation of homogeneous pseudo-interpenetrating polymer networks
  • as photosensitive agent in the preparation of photosensitive benzocyclobutene-functionalized siloxane thermosets

Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H228

Precautionary Statements

P210

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis and characterization of photosensitive benzocyclobutene?functionalized siloxane thermosets.
Zuo X, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 47(22), 6246-6258 (2009)
Tuning the free volume cavities of polyimide membranes via the construction of pseudo-interpenetrating networks for enhanced gas separation performance.
Low BT, et al.
Macromolecules, 42(18), 7042-7054 (2009)

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