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Sigma-Aldrich

Molybdenumhexacarbonyl

98%

Synonym(s):

Hexacarbonylmolybdenum(0)

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About This Item

Linear Formula:
Mo(CO)6
CAS Number:
Molecular Weight:
264.00
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:

vapor density

9.1 (vs air)

Assay

98%

form

solid

reaction suitability

core: molybdenum
reagent type: catalyst

bp

156 °C (lit.)

mp

150 °C (dec.) (lit.)

density

1.96 g/mL at 25 °C (lit.)

SMILES string

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI key

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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General description

Molybdenumhexacarbonyl is a white crystalline solid, melts at 150oC, density 1.96 gm/cc, is insoluble in water and soluble in most organic solvents.

Application

Used in the grafting of silica, as a catalyst for epoxidation of olefins,in the adsorption of organosulfur compounds from liquid fuels,as a precursor for the manufacture of organomolybdenum dyes and for Molybdenum plating by thermal decomposition.

Pictograms

Skull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Selective adsorption of dibenzothiophene by functionalized metal organic frameworks sorbents
Shi F, et al
Applied Catalysis. B, Environmental, 103(3-4), 261-265 (2011)
Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor
Abrantes M, et al
Catalysis Communications, 15(1), 64-67 (2011)
Advanced Synthesis & Catalysis, 352(10), 1759-1769 (2010)
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative

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